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Pozycja Open Access Rheological, Mechanical, Microstructural and Radiation Shielding Properties of Cement Pastes Containing Magnetite (Fe3O4) Nanoparticles(Springer Nature, 2023-01) Sikora, Pawel; El-Khayatt, Ahmed M.; Saudi, H.A.; Liard, Maxime; Lootens, Didier; Chung, Sang-Yeop; Woliński, Paweł; Abd Elrahman, Mohamed; Faculty of Civil and Environmental Engineering, West Pomeranian University of Technology in Szczecin, Poland; Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University, (IMSIU), Riyadh, Saudi Arabia; Department of Physics, Faculty of Science, Al-Azhar University, Women Branch, Nasr City, Cairo, Egypt; Sika AG, Switzerland; Department of Civil and Environmental Engineering, Sejong University, Seoul 05006, Republic of Korea; Faculty of Applied Sciences, Collegium Mazovia Innovative School, 08-110 Siedlce, Poland; Structural Engineering Department, Mansoura University, Mansoura City 35516, EgyptThis work examines the influence of iron oxide nanoparticles (Fe3O4 NPs) on neutron and gamma-ray radiation shielding characteristics of Portland cement paste. Experimental evaluations were supplemented with theoretical studies using NXCom program. Portland cement pastes with 5, 10, 15, 20, and 30 wt% of nanomagnetite cement replacement were produced. Moreover, rheological, early strength development, compressive strength, and mercury intrusion porosimetry (MIP) tests were performed. The results showed that increasing the amount of Fe3O4 NPs in a mix leads to a gradual increment in measured viscosity and yield stress. High nano-Fe3O4 content substantially impeded the early strength development process and led to a decrement in the 7- and 28-day compressive strength of cement paste. The MIP studies exhibited a gradual increment in total porosity, and average pore volume, as nano-Fe3O4 content was increased. All the macroscopic cross-sections of slow, fast and thermal neutrons constantly increased as a result of the addition of magnetite nanoparticles, with their variations being markedly linear. Similarly, gamma attenuation test results indicated that the addition of Fe3O4 powder enhances the shielding capability of paste in the energy range of interest (0.08–2.614 MeV). In conclusion, Fe3O4 nanoparticles can be successfully used in producing lead-free cementitious composites with improved gamma-ray and neutron shielding properties. However, certain drawbacks related to an increment in matrix porosity and thus a decrement in mechanical performance should be taken into account.